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Catalogs Discussion Forums -> Physical Chemistry -> A mixture of CO and CO2 have a density of 1.5g/L at 30*C and 730 mm pressure.What is the composition -> Go to message
This Post 0 points    (Olaaa!! Perrrfect answer.   in 0 votes )   [?]
  • Assume ideal behaviour of both gases.
  • Let the mixture of gas contain x gram of Carbon monoxide and y gram of carbon dioxide.
  • Let the total volume occupied by the mixture be V l
  • Now, since the density of the mixture is 1.5g/l, the mass of mixture is 1.5V g
  • i.e. x+y = 1.5V......(1)
  • further since PV=nRT ,  n = PV/RT
  • i.e. no. of moles of mixture = PV/RT
  • i.e. x/28 + y/44 = n....(2)
  • Solve for x and y in terms of V
  • since P= 73/76 atm, R=0.0821, T=300K
  • we have n = 0.04V (approx)
  • x/28 + y/44 = 0.04V....(3)
  • solve (1) and (3) simultaneously in for x,y in terms of V.
  • 49.28V = 44x+28y...(4)
  • solve for x and y in terms of V using 1 and 4
  • calculate the composition hence

 

 

Catalogs Discussion Forums -> Organic Chemistry -> What is the Chemical Test to differentiate Aniline from Methylamine? -> Go to message
This Post 0 points    (Olaaa!! Perrrfect answer.   in 0 votes )   [?]

 

The diazonium salt test

Methylamine is a primary amine so cooling and treatment with NaNO2/HCl will liberate nitrogen gas only.

In case of aniline, treatment with NaNO2/HCl after cooling leads to dizotisation, which forms a diazonium salt. Addition of a alkaline beta-naphthol(2-naphthol in NaOH) produces a red/orange dye.

Methylamine, being a primary amine, would not give a dye.It'll evolve a continuous stream of nitrogen gas when you cool it and then add NaNO2/HCl

Catalogs Discussion Forums -> Mechanics -> The blocks B anc C in the figure have mass m each. The strings AB and BC are light, having -> Go to message
This Post 9 points    (Olaaa!! Perrrfect answer.   in 3 votes )   [?]

Consider C

Resolve the Tension into horizontal and vertical components,

U have,

T2sin(theta2)=mg

T2cos(theta2)=mg

implies theta2 = 45 degree

Also using these we get T2=sqrt(2)mg

Now considering the block B

T1sin(theta1)=T2sin(theta2)

and, T1cos(theta1)=mg+T2cos(theta2)

Using these, we get T1=sqrt(5)mg

Hence option C

Catalogs Discussion Forums -> Integral Calculus -> please help me integrate (x-a)*(x-b)*(x-c)...........(x-z)dx -> Go to message
This Post 0 points    (Olaaa!! Perrrfect answer.   in 0 votes )   [?]

it's a no-brainer.

since the series also has an (x-x) =0

so value of product=0

Answer =0

Catalogs Discussion Forums -> Mechanics -> Is dopplers effect applicable.when the velocity of object and receiver are perpendicular to each oth -> Go to message
This Post 0 points    (Olaaa!! Perrrfect answer.   in 0 votes )   [?]

Doppler effect is a result of relative motion between source and receiver along the line joining them.  So we need to consider the component of source and receiver velocity along the line joining them. If these components are zero or are such that their vector sum is zero, then there is no doppler effect.

So when the source and receiver are both in motion, doppler effect is still observed because there is still some relative motion along the joining them, even if the velocities are perpendicular.

However this wont be the case if the velocities are parallel. In that case there is no relative motion along the line joining source and observer.

 

Catalogs Discussion Forums -> Mechanics -> A body of weight 9.8 N is kept on a table which exerts a force of 10 N on the body -> Go to message
This Post 10 points    (Olaaa!! Perrrfect answer.   in 2 votes )   [?]

Upward force exerted by Table= 10N

Therefore by Newton's third law of motion, the block exerts an equal downward force on the table

hence A

Further, since the net upward force is greater than the net downward force(weight), the body has an upward acceleration.

This is as if the system is placed in a lift accelerating upward. Hence the contact force is greater than the body's weight.

so A and D are correct.

Catalogs Discussion Forums -> Differential Calculus -> vwho can prove 1=2,2=3,3=4.......exept me -> Go to message
This Post 0 points    (Olaaa!! Perrrfect answer.   in 0 votes )   [?]

Crap.

You guys would do a lot better to abandon such nonsense and study.

Catalogs Discussion Forums -> Algebra -> If the ratio of the roots of the equation ax2+bx+c=0 be equal to the ratio of roots of the equation -> Go to message
This Post 0 points    (Olaaa!! Perrrfect answer.   in 0 votes )   [?]

Let m and n be the roots of the first equation

Therefore, we can find a number, say k, such that km and kn are the roots of the second equation

 now m+n = -b/a

k(m+n) = -q/p

i.e. k=aq/bp

further  mn=c/a

and k2(mn) = r/p

so  use k= aq/bp and mn=c/a

so that a2q2/b2p2(c/a)  = r/p

i.e. caq2 = rpb2

 

 

Catalogs Discussion Forums -> Trignometry -> find the sum cos pi/7 + cos 3pi/7 + cos 5pi/7 ans 1/2 -> Go to message
This Post 5 points    (Olaaa!! Perrrfect answer.   in 1 votes )   [?]

Yes there is. But this is how it is derived. It's easier to remember this than cram the formula.

In general in the cosine series were the angles are in AP, such as this, you multiply and divide by the sine of the common difference and then simplify using the defactorization formulae.

Catalogs Discussion Forums -> Trignometry -> find the sum cos pi/7 + cos 3pi/7 + cos 5pi/7 ans 1/2 -> Go to message
This Post 7 points    (Olaaa!! Perrrfect answer.   in 2 votes )   [?]

Multiply and divide by sin(2pi/7)

 

so we have {sin(2pi/7)(cospi/7) + sin(2pi/7)cos(3pi/7) + sin(2pi/7)cos(5pi/7)}(1/sin(2pi/7)

 = {1/2sin(2pi/7)} { sin(3pi/7) + sin(pi/7) + sin(5pi/7) - sin(pi/7) + sin(pi) - sin(3pi/7)}

since sin(pi-x) = sinx

the expression becomes

= {0.5/sin(2pi/7)} { sin(pi-5pi/7} = {0.5/sin(2pi/7)}{sin(2pi/7)} = 0.5

Catalogs Discussion Forums -> Algebra -> prove that the roots of the equation(a4+b4) +4(abcd)x+(c4+d4) cannot be different if real. -> Go to message
This Post 10 points    (Olaaa!! Perrrfect answer.   in 2 votes )   [?]

Consider the discriminant of the equation,

D= 16(a2b2c2d2) - 4(a4+b4)(c4+d4)

  =  16(a2b2c2d2) - 4(a4b4) -4(a4d4) - 4(b4c4) - 4(b4d4)

 = 4a2b2(c2d2-a2b2) + 4a2d2(b2c2-a2d2) + 4b2c2(a2d2-b2c2) + 4c2d2(a2b2-c2d2)

= -4(a2b2-c2d2)2 - 4(b2c2-a2d2)2

Clearly D<=0

The roots can be real only for D=0 , that is when the two terms are simultaneously equal to zero.

So the roots have to be equal if they are real.

Catalogs Discussion Forums -> Algebra -> Where will i get proof for e to the power i(iota)*theta? -> Go to message
This Post 12 points    (Olaaa!! Perrrfect answer.   in 3 votes )   [?]

The proof is using the Maclaurin Series

f(x) = f(0) + f'(0)x + f''(0)x2/2! + f'''(0)x3/3! + ............... ad inf.

So cosx = 1 - x2/2! + x4/4!+........ad inf.

and sinx = x-x3/3! - x5/5! + ......ad inf.

and ex = 1+x + x2/2! + x3/3! + x4/4! + .......................ad inf.

Now we have to prove that, cosx + isinx = eix

 

LHS = cosx+isinx

Use the above expansions, and multiply the sine expansion by "i" .

RHS = eix,

Expand using the above expression, and substitute ix instead of x.

You will see that  LHS = RHS.

Catalogs Discussion Forums -> Algebra -> Prove that -> Go to message
This Post 10 points    (Olaaa!! Perrrfect answer.   in 2 votes )   [?]

Straightforward.

 

Apply the AM>=GM inequality.

For 10 numbers, a2,b2,c2,d2,ab,bc,ca,ad,bd,cd,

 

(a2+b2+c2+d2+ab+bc+ca+ad+bd+cd)/10 >= {a2b2c2d2(ab)(bc)(ca)(ad)(bd)(cd)}1/10

                                                                       >= {(abcd)2(abcd)3}1/10

                                                                     >=1  (since abcd=1)

Therefore, LHS>=10

Catalogs Discussion Forums -> Non IIT Institutes -> whAT is the ranking of mumbai institute of chem technology(udct)?>? -> Go to message
This Post 12 points    (Olaaa!! Perrrfect answer.   in 3 votes )   [?]

As per the HT mint survey,

11th best government college in India, after 7 IITs,ITBHU,Anna and Jadavpur. Ranked higher than NITs and ISMU.

It's got one of the best chemical technology research programmes in the world. Its research output is much higher  than even IITs.

Its Chemical Engineering dept. has been ranked by UGC as the best in India.

But not many people know about it, surprisingly enough.

This year, as far as I remember, chem.engg cutoffs for open cat. were

  AIR 9000 odd (thru AIEEE)

and 187/200(MHT-CET)

There are about 75 seats in all for chemical engineering.(including reserved.)

there are 22 seats to be filled  through AIEEE in chemical engg.

The rest are filled through MHTCET. 

If you are really interested in chemical engineering, or are getting chemical engineering everywhere else, then ICT is the place for you. (Except possibly  IITs)

according to most people, in case of chem.engg., UDCT~IIT B> any other college in India.

Also UD has an excellent reputation with foreign universities and strong linkages with the chemical industry. Mukesh Ambani  studied here.

 

.

Catalogs Discussion Forums -> Electricity -> well, i know that what is the potential inside as well as outside a sphere but on the surface the el -> Go to message
This Post 0 points    (Olaaa!! Perrrfect answer.   in 0 votes )   [?]

The electric field on the surface of a uniformly charged hollow sphere is discontinuous.

But its value ( magnitude) is the right hand derivative of the potential function at the surface.

i.e. Kq/R2

 

 

Catalogs Discussion Forums -> Thermal Physics -> 1 mole of an ideal gas ( monoatomic ) is heated at a constant pressure of 1 atm from o to 100 deg c. -> Go to message
This Post 0 points    (Olaaa!! Perrrfect answer.   in 0 votes )   [?]

 

Straightforward.

Work done is = nRT where T is the rise in temperature, n  is the no. of moles of gas.

So Work=R(100)

=100R?

Community shelf Community shelf -> WHY THIS COUNTRY AIN'T CHANGING???? -> Go to message
This Post 0 points    (Olaaa!! Perrrfect answer.   in 0 votes )   [?]
Look, I don't see anything new here. Everyone knows that ultimately it is a person's character which determines his/her position, and NOT the kind of education he/she receives. Some of the biggest achievers of the 20th century were essentially people who didn't even receive proper formal education. Of course, we've all been conditioned to believe that IIT/IIM/MS/MBA=success/happiness.Everything else is trash. But the more sensible people are aware of the truth. Infact, I myself would prefer eating with a nice roadside beggar than some of the arrogant IIT/IIM fellows, however polished they may be. But the brutal reality is that the education system,especially ours, makes one literate but not necessarily educated. And there's a hell lot of difference between the two. The beggar was educated. The IIT/IIM fellow was merely literate.So there's nothing new in whatever you've written. But yes, it is nice writing. Lucid and good vocabulary.
Catalogs Discussion Forums -> Electricity -> jaate jaate ek formula thats self derived .... -> Go to message
This Post 5 points    (Olaaa!! Perrrfect answer.   in 1 votes )   [?]

Ya, bbye :)

Catalogs Discussion Forums -> Physical Chemistry -> how can the volume of gas be negative?/ below -273k it's possible it seems..ya i know that temper -> Go to message
This Post 7 points    (Olaaa!! Perrrfect answer.   in 2 votes )   [?]

 Lol, I don't think this has any physical meaning at all. Volume is the space occupied by a body, When volume becomes negative, what are you trying to say? More space is going to be created? LOL

See, questions like negative mass, negative volume are meaningless in a physical sense. Don't get confused by looking at the mathematics. Physicists first see things and then use the math, not the other way round

Catalogs Discussion Forums -> Analytical Geometry -> find whether the point(2,6) lies on,inside or outside the parabola 2x - y^2 + 2y +3 =0..... plssss a -> Go to message
This Post 15 points    (Olaaa!! Perrrfect answer.   in 3 votes )   [?]

Convert the equation into the standard form y2=4ax

After some manipulation, you see that

(y-1)2=2(x+2)

Shifting the origin to the point (1,-2)

Y=y-1 and X=x+2

Y2=2X

Now the position of the given point w.r.t. new coordinate system is,

X1=x1+2=2+2=4

and Y1=y1-1=6-1=5

So: (4,5)

Now insert this in the original equation, clearly S1>0(=25-8=17)

Outside.

 
 
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